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    Section 1 — Product and Company Identification

    Chemical Name
    CAS Number
    No components of this mixture with known CAS numbers are present in concentrations exceeding the threshold subject to the reporting requirements of SARA Title III, Section 313.
    Synonyms
    Primary Use
    Crop residue degradation complement
    Company Information

    Corporate Headquarters

    The Mosaic Company
    101 East Kennedy Blvd, Ste 2500
    Tampa, FL 33602

    US Guarantor

    Mosaic Biosciences
    Headquarters
    5 Lab Drive, Suite 3200
    Durham, NC 27709
    Production
    111 E. Tever Street
    Plant City, FL 33563-2417

    Canada Guarantor

    Mosaic Canada Crop Nutrition, LP
    1700 – 2010 12th Ave.
    Regina, SK Canada S4P 0M3

    Contact Info

    www.cropnutrition.com
    +1 (813) 718-7284
    MBNAinfo@mosaicco.com

    Emergency Contacts

    24 Hour Emergency Telephone Number:
    For Chemical Emergencies:
    Spill, Leak, Fire or Accident
    Call CHEMTREC
    North America: (800) 424-9300 (reference CCN201871)
    Others: (703) 527-3887 (collect)

    Section 2 — Hazard Identification

    OSHA / HCS Status
    This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See appropriate classifications below.
    GHS Classification
    Signal Word : Warning
    Hazard Statement(s)
    SKIN IRRITATION
    Warning Harzard

    Category 2

    EYE IRRITATION

    Category 2

    GHS Classification
    SKIN IRRITATION
    EYE IRRITATION
    Signal Word : Warning
    Hazard Statement(s)
    Warning Harzard

    Category 2

    Category 2

    Label Elements

    Prevention

    Wear eye or face protection.

    Response

    IF IN EYES:

    Rinse cautiously with water for several minutes. Remove contact lenses, if
    present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.

    Storage

    Disposal

    Section 3 — Composition Information on Ingredients

    Formula
    Composition
    3(2H)-Isothiazolinone,5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-isothiazolone 55965-84-9 0.001 – 0.01%
    1,2-benzisothiazol-3(2H)-one; 1,2- benzisothiazolin-3-one 2634-33-5 0.001 – 0.01%
    Zinc sulfate monohydrate 7446-19-7 0.01 – 0.5%
    Copper sulfate pentahydrate 7758-99-8 0.1 – 1%
    Sodium hydroxide 1310-73-2 1 – 5%
    Citric acid 77-92-9 1 – 5%

    Section 4 — First Aid Measures

    First Aid Procedures

    Eyes:

    Move victim away from exposure and into fresh air. Flush eyes with plenty of clean water for at least 15 minutes. If symptoms persist, seek medical attention.

    Skin:

    Wash contaminated area thoroughly with mild soap and water. If chemical or solution soaks through clothing, remove clothing and wash contaminated skin. If irritation develops and persists after washing, seek medical attention.

    Inhaled:

    If respiratory symptoms develop, move victim away from source of exposure and into fresh air. If symptoms persist, seek medical attention.

    Ingestion:

    Rinse mouth thoroughly. If large amounts are swallowed, seek emergency medical attention.
    Note to Physician

    Section 5 — Fire Fighting Measures

    Extinguishing Media
    Use extinguishing agent suitable for type of surrounding fire. Foam, dry powder, carbon dioxide, water spray, sand.
    Protection of Firefighters
    Positive pressure, self-contained breathing apparatus is required for all firefighting activities involving hazardous materials.

    Section 6 — Accidental Release Measures

    Response Techniques

    Section 7 — Handling and Storage

    Handling
    Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Wash contaminated clothing or shoes. Use good personal hygiene practices.
    Storage
    Use and store this material in dry, well-ventilated areas. Store only in approved containers. Keep container(s) tightly closed. Avoid excessive heat and direct sunlight.

    Section 8 — Exposure Controls / Personal Protection

    Engineering Controls
    Use process enclosure, general dilution ventilation or local exhaust systems where necessary to maintain airborne dust concentration below the OSHA standards or in accordance with applicable regulations.
    Personal Protective Equipment (PPE)

    Eye/Face:

    Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended.

    Skin:

    Wear gloves, pants, long sleeved shirt, shoes and socks.

    Respiratory:

    Under normal conditions, none required. If drift occurs, wear breathing apparatus.

    Other:

    A source of clean water should be available in the work area for flushing eyes and skin.

    General Hygiene Considerations
    Wash thoroughly after handling and use adequate ventilation
    Exposure Guidelines

    Copper Sulfate Pentahydrate

    As Cu, PEL
    0.2 mg/m3 as fume
    1 mg/m3 as dusts and mists

    Sodium Hydroxide, 50%

    PEL-TWA: 2 mg/m3

    Manganese Sulfate Monohydrate

    As Mn compound or fume, PEL-ceiling: 5
    mg/m3

    Sodium Molybdate Dihydrate

    As Mo,
    Soluble: 5 mg/m3
    Insoluble: 15 mg/m3

    Glycerin

    PEL-TWA: 15/mg/mL3 (total dust)
    PEL-TWA: 5 mg/mL3 (respirable)

    Section 9 — Physical and Chemical Properties

    Note :

    Appearance

    lear blue liquid

    Vapor Pressure (mm Hg)

    Not applicable

    Odor

    Minimal, earthy

    Vapor Density (air=1)

    Not applicable

    Odor Threshold

    No data available

    Specific Gravity or Relative Density

    1.19

    Physical state

    Liquid

    Bulk Density

    1.18 – 1.20 g/cm3 (densimeter)

    pH

    6.0 – 8.0

    Solubility in Water

    Dispersible in water

    Melting Point/ Freezing Point

    No data available

    Partition coefficient

    Not applicable

    Boiling Point

    No data available

    Auto-Ignition Temperature

    No data available

    Flash Point

    No data available

    Decomposition Temperature

    No data available

    Evaporation Rate

    No data available

    Viscosity

    No data available

    Flammability

    No data available

    Volatility

    <1 %

    Upper/Lower Flammability or explosive limits

    No data available

    Section 10 — Stability and Reactivity

    Chemical Stability

    Stable under normal conditions. Susceptible to extreme conditions and prolonged excessive heat.

    Conditions to Avoid

    Prolonged or excessive heat and open flame, direct sunlight, and freezing.

    Incompatible Materials

    Strong oxidizing agents, strong reducing agents, acids, bases, direct sunlight, nitrates.

    Hazardous Decomposition Products

    Hazardous oxides may form with decomposition. Under extreme conditions, irritating gases may form.

    Section 11 — Toxicological Information

    Causes skin irritation and serious eye irritation.

    Section 12 — Ecological Information

    Toxicity:

    Likely to be toxic to fish, aquatic invertebrates, and plants when concentrated.

    Persistence and degradability:

    Persistence is unlikely based on available information.

    Bioaccumulation potential:

    No additional information available.

    Mobility in soil:

    Likely to be mobile in the environment due to solubility in water.

    Results of PBT and vPvB assessment:

    This product contains no PBT/vPvB chemicals

    Endocrine disrupting properties:

    This product contains no endocrine disrupting chemicals.

    Section 13 — Disposal Considerations

    Container disposal: Triple rinse containers before disposal. Add rinsings to spray tank. DO NOT reuse this container for any other purpose. If recycling, replace cap and return clean container to recycler or designated collection point. If not recycling, break, crush or puncture and deliver to an approved waste management facility. Product disposal: Do not dispose of undiluted chemicals on site. Dispose of this product only by using according to the label, or at an approved landfill. DO NOT contaminate water supply with chemical or empty container.

    Section 14 — Transport Info

    Regulatory Status

    Not regulated as dangerous goods by DOT, TDG, IMDG, or IATA.

    Identification Number

    Hazard Class

    Proper Shipping Name

    Packing Group

    DOT Emergency Response Guide Number

    Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

    MARPOL Annex V

    IMO/IMDG

    Section 15 — Transport Info

    SARA Title III

    (Exemptions at 40 CFR, Part 370 may apply for agricultural use, or for quantities of less than 10,000 pounds on-site.)

    Section 311/312

    TSCA

    All components of this product are exempt from listing on the United States EPA TSCA Chemical Inventory and not otherwise regulated by TSCA.

    WARNING: Cancer and reproductive Harm – www.P65Warnings.ca.gov

    Section 16 — Other Information

    Disclaimer

    The information in this document is believed to be correct as of the date issued. HOWEVER, MOSAIC MAKES NO GUARANTEE, REPRESENTATION, OR WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE REGARDING THE ACCURACY OR COMPLETENESS OF THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO THE USE OF THIS PRODUCT. User is responsible for determining whether this product is fit for a particular purpose and suitable for user’s method of use or application and assumes the risk of use thereof. The conditions and use of this product are beyond the control of Mosaic, and Mosaic disclaims any liability for loss or damage incurred in connection with the use or misuse of this product. Each user should review the recommended industrial hygiene and safe handling procedures in the specific context of the intended use and determine whether they are appropriate.

    Preparation
    The preparation of this SDS was in accordance with ANSI Z400.1-2010.

    Other Hazard Classifications

    NFPA HAZARD CLASS

    Health

    Flammability

    Instability

    Special Hazard

    HMIS HAZARD CLASS

    Health

    Flammability

    Physical Hazard

    PPE

    WHMIS 2015 (HPR) HAZARD CLASS