- Section 1 - Product and Company Identification
- Section 2 — Hazard Identification
- Section 3 — Composition Information on Ingredients
- Section 4 — First Aid Measures
- Section 5 — Fire Fighting Measures
- Section 6 — Accidental Release Measures
- Section 7 — Handling and Storage
- Section 8 — Exposure Controls / Personal Protection
- Section 9 — Physical and Chemical Properties
- Section 10 — Stability and Reactivity
- Section 11 — Toxicological Information
- Section 12 — Ecological Information
- Section 13 — Disposal Considerations
- Section 14 — Transport Info
- Section 15 — Regulatory Information
- Section 16 — Other Information
Safety Data Sheet
Section 1 — Product and Company Identification
Monobasic Ammonium Phosphate
Ammonium Dihydrogen Phosphate
Ammonium Phosphate Monobasic
Powdered MAP (PMAP)
Standard MAP (SMAP)
Fertilizer Grade Ammonium Phosphate
MAP 10 – 49 – 0
The Mosaic Company
101 East Kennedy Blvd, Ste 2500
Tampa, FL 33602
Mosaic Global Sales, LLC
13830 Circa Crossing Drive
Lithia, FL 33547
Mosaic Canada Crop Nutrition, LP
1700 – 2010 12th Ave.
Regina, SK Canada S4P 0M3
(800) 918-8270 or (813) 775-4200
Section 2 — Hazard Identification
H315: Causes skin irritation
H320: Causes eye irritation
H315: Causes skin irritation
H320: Causes eye irritation
Wash hands thoroughly after handling.
Wear protective gloves
IF ON SKIN: Wash with plenty of water.
Specific Treatment, see supplemental first aid information.
If skin irritation occurs: Get medical advice/attention.
Take off contaminated clothing and wash it before reused.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337 + P317
If eye irritation persists: Get medical help.
Disposal of content/containers to be in accordance with local/regional/national regulations.
Section 3 — Composition Information on Ingredients
|Monobasic Ammonium Phosphate||CAS 7722-76-1||70-90%|
|Ammonium Sulfate||CAS 7783-20-2||5.5-7.5%|
Section 4 — First Aid Measures
First Aid Procedures
Note to Physician
Section 5 — Fire Fighting Measures
Protection of Firefighters
Section 6 — Accidental Release Measures
Section 7 — Handling and Storage
Section 8 — Exposure Controls / Personal Protection
Personal Protective Equipment (PPE)
Approved eye protection to safeguard against potential eye contact, irritation, or injury is recommended.
The use of cloth or leather work gloves is advised to prevent skin contact, possible irritation and absorption.
A NIOSH approved air purifying respirator with a type 95 (R or P) particulate filter may be used under conditions where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited (see manufacturer’s respirator selection guide). Use a positive pressure air supplied respirator if there is potential for uncontrolled release, exposure levels are not known or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed if workplace conditions warrant a respirator.
A source of clean water should be available in the work area for flushing eyes and skin.
General Hygiene Considerations
OSHA Permissible Exposure Limits (PEL):
Particulates Not Otherwise Regulated:
5 mg/m3 TWA (respirable);
15 mg/m3 TWA (total)
50 ppm (35 mg/m3) TWA
ACGIH Threshold Limit Value (TLV):
Particulates Not Otherwise Specified:
3 mg/m3 TWA (respirable);
10 mg/m3 TWA (inhalable)
25 ppm (18 mg/m3) TWA;
35 ppm (27 mg/m3) STEL
Section 9 — Physical and Chemical Properties
Vapor Pressure (mm Hg)
Vapor Density (air=1)
Specific Gravity or Relative Density
Solubility in Water
Melting Point/ Freezing Point
Upper/Lower Flammability or explosive limits
Section 10 — Stability and Reactivity
Conditions to Avoid
Hazardous Decomposition Products
Section 11 — Toxicological Information
Powdered Monoammonium Phosphate
Acute Oral Toxicity
Acute Inhalation Toxicity
Acute Dermal Toxicity
Section 12 — Ecological Information
May release ammonium ions that are toxic to fish. Un-ionized ammonia concentrations above 0.02 mg/l are considered toxic in fresh water. May release phosphates which will result in algae growth, increased turbidity, and depleted oxygen. At extremely high concentrations, this may be hazardous to fish or other marine organisms. Release to watercourses may cause effects downstream. Fish 96 hour LC50, OECD Guidelines 203 (rainbow trout): >86mg/L.
Section 13 — Disposal Considerations
Section 14 — Transport Info
Proper Shipping Name
DOT Emergency Response Guide Number
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
MARPOL Annex V
Section 15 — Transport Info
SARA Title III
NTP, IARC, OSHA
Canada DSL and NDSL
CA Proposition 65
WARNING: Cancer and reproductive Harm – www.P65Warnings.ca.gov
Section 16 — Other Information
The information in this document is believed to be correct as of the date issued. HOWEVER, MOSAIC MAKES NO GUARANTEE, REPRESENTATION, OR WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR PURPOSE REGARDING THE ACCURACY OR COMPLETENESS OF THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO THE USE OF THIS PRODUCT. User is responsible for determining whether this product is fit for a particular purpose and suitable for user’s method of use or application and assumes the risk of use thereof. The conditions and use of this product are beyond the control of Mosaic, and Mosaic disclaims any liability for loss or damage incurred in connection with the use or misuse of this product. Each user should review the recommended industrial hygiene and safe handling procedures in the specific context of the intended use and determine whether they are appropriate.